This report describes and analyzes a derailment which occurred when a train separation resulted in unequal deceleration of the two parts of the train. Unusual lateral forces at the rear of the third locomotive unit canted the outside rail of a 3 30' curve outward enough to allow the wheels to drop inside. A tank car of propane was punctured and the ensuing fire impinged other tank cars and caused the violent rupture of three of them. Fifty-four person were injured by the fire and rocketing parts of tank cars.